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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2020 · Mains Paper II

Q3. Formula units in rock-salt KCl

Question

KCl has rock-salt structure and density 1.98 g cm⁻³. Its first-order (200) reflection is at 6.5° for X-rays of wavelength 70.8 pm. Calculate formula units per unit cell.

Answer in brief

The calculation gives Z≈3.91≈4 KCl formula units per conventional cell.

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As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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CoversFormula units in rock-salt KClCrystallography