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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2021 · Mains Paper II

Q7. Particle in a box: probability between L/4 and 3L/4

Question

What is the probability of locating a particle in one-dimensional box between L/4 and 3L/4, where L is the length of the box? Assume the particle to be in the lowest energy state.

Answer in brief

P = 1/2 + 1/π = 0.818: there is an 82 % probability of finding the particle in the middle half of the box (classical value 50 %).

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Coversparticle in a boxprobabilityBorn interpretationground state wave functioncorrespondence principle