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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2023 · Mains Paper II

Q8. Atomic weight of ¹⁵N from the rotational lines of NO

Question

The rotational absorption of ¹⁴N¹⁶O is observed at 50121.15 Hz and that of ¹⁵N¹⁶O at 48375.05 Hz. Calculate the atomic weight of ¹⁵N. [Mass of ¹⁴N = 14.007; mass of ¹⁶O = 15.9994]

Answer in brief

m(¹⁵N) = 14.99 u ≈ 15.0 u.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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Coversrotational spectroscopyisotope effectreduced massrigid rotormicrowave spectrum of NO