UPSC Combined Geo-Scientist, Mains · 2026 · Mains Paper II
Q12(b). Quantum yield from an actinometer
Question
In a photochemical reaction, the following data were obtained using an actinometer: number of photons absorbed per second =2.0×10¹⁶; rate of formation of product molecules =3.6×10¹⁶ molecules s⁻¹. (i) Calculate the quantum yield of the reaction. (ii) What does the obtained value indicate about the nature of the mechanism? (iii) Name one reaction from the syllabus where such behaviour is observed. Explain your choice.
Model answer
The free solution for 2026 answers the questions picked in its time plan. Question 12 is answered in full in the Book Edition of the 2026 solutions of Geo-Scientist Chemistry Paper II.
Coversquantum yieldQuantum yield from an actinometer
All parts of Question 12
- 12(a) A unimolecular reaction is second order at low pressure10 marks
- 12(b) Quantum yield from an actinometer10 marks