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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2026 · Mains Paper II

Q7. ΔᵣH^° from the temperature dependence of E^°

  • 10 marks
  • Topic: Electrochemistry
  • Question only
Question

The T-dependence of E^° of a galvanic cell is given by E^°=A+BT+CT². Find the expression of ΔᵣH^° for the cell reaction. Show that when T→∞ the ΔᵣG^° and ΔᵣH^° are the same.

Model answer

The free solution for 2026 answers the questions picked in its time plan. Question 7 is answered in full in the Book Edition of the 2026 solutions of Geo-Scientist Chemistry Paper II.

Coversthermodynamics of cellsΔᵣH^° from the temperature dependence of E^°

All parts of Question 7

  • 7 ΔᵣH^° from the temperature dependence of E^°10 marks