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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper III covers analytical and organic chemistry.

UPSC Combined Geo-Scientist, Mains · 2018 · Mains Paper III

Q6(b). Conjugate addition and dehydrogenation

Question

Cyclohex-2-en-1-one reacts with MeMgBr/CuCN to C, then PhSeCl and H₂O₂ to D.

Answer in brief

C is the 3-methylcyclohexanone enolate; D is 3-methylcyclohex-2-en-1-one.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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Read the whole 2018 solution2018 question paper

CoversConjugate additiondehydrogenationEnolate chemistry

All parts of Question 6