UPSC Combined Geo-Scientist, Mains · 2019 · Mains Paper III
Q1(b). Nanomolar concentration to ppb
Question
C₂₉H₆₀ in rainwater has concentration 5.6 nM. Express it in ppb.
Answer in brief
Approximately 2.29 ppb by mass, assuming water density 1.00 kg/L.
Key points
- Molar mass is 29(12.011)+60(1.008)=408.799 g/mol.
- Mass concentration is 5.6×10⁻⁹(408.799)=2.2893×10⁻⁶ g/L, or 2.2893 μg/L.
- In dilute water of density about 1 kg/L, 1 μg/L≈1 μg/kg=1 ppb.
- Hence the concentration is about 2.3 ppb to the precision of the input.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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All parts of Question 1
- 1(a) Activity-coefficient trends5 marks
- 1(b) Nanomolar concentration to ppb5 marks
- 1(c) Buffer capacity and dilution5 marks
- 1(d) Washing the flask walls5 marks
- 1(e) Observation zone in a flame5 marks
- 1(f) Proximate coal analysis5 marks
- 1(g) Volumetric manganese in steel5 marks
- 1(h) Gradient elution5 marks