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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper III covers analytical and organic chemistry.

UPSC Combined Geo-Scientist, Mains · 2019 · Mains Paper III

Q1(b). Nanomolar concentration to ppb

Question

C₂₉H₆₀ in rainwater has concentration 5.6 nM. Express it in ppb.

Answer in brief

Approximately 2.29 ppb by mass, assuming water density 1.00 kg/L.

Key points

  • Molar mass is 29(12.011)+60(1.008)=408.799 g/mol.
  • Mass concentration is 5.6×10⁻⁹(408.799)=2.2893×10⁻⁶ g/L, or 2.2893 μg/L.
  • In dilute water of density about 1 kg/L, 1 μg/L≈1 μg/kg=1 ppb.
  • Hence the concentration is about 2.3 ppb to the precision of the input.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(b), 2019 Mains Paper III: solution pages 1 and 2
Solution pages 1 and 2 of 19

CoversNanomolar concentration to ppbTrace concentration units