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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2020 · Paper II, Chemistry · Q91 of 120

Geo-Scientist Prelims 2020 Chemistry Q91: Consider the following compound [A]:

QuestionStereochemistry / Fischer projections

Consider the following compound [A]:

UPSC Combined Geo-Scientist Prelims 2020 Paper II (Chemistry), Q91: figure printed with the question

Which one of the following represents an enantiomer of [A]?

UPSC Combined Geo-Scientist Prelims 2020 Paper II (Chemistry), Q91: answer options as printed
  1. (a) Fischer projection (a)
  2. (b) Fischer projection (b)
  3. (c) Fischer projection (c)
  4. (d) Fischer projection (d)

Answer: (d)

[A] is (2S,3R)-2-bromo-3-methylpentane. Enantiomer must invert both centres → (2R,3S). Assigning CIP to options: (a) 2R,3R; (b) 2R,3R; (c) 2R,3R; (d) 2R,3S → (d). Trick: lowest priority (H) on a horizontal bond → reverse the observed sense.

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