QuestionStereochemistry / counting isomers
The total number of optical isomers possible for cholesterol is:

- (a) 128
- (b) 256
- (c) 64
- (d) 512
Answer: (b) 256
Cholesterol has 8 stereocentres (C3, C8, C9, C10, C13, C14, C17, C20). Maximum stereoisomers = 2⁸ = 256 → (b). Only one occurs naturally.