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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2023 · Paper II, Chemistry · Q50 of 120

Geo-Scientist Prelims 2023 Chemistry Q50: Considering U as a function of variables T and V, which one of the…

QuestionThermodynamics / partial derivatives

Considering U as a function of variables T and V, which one of the following expressions is correct for \(\left(\frac{\partial U}{\partial p}\right)_T\) ?

  1. (a) \(\left(\frac{\partial U}{\partial p}\right)_T = \left(\frac{\partial U}{\partial V}\right)_T \left(\frac{\partial V}{\partial p}\right)_T\)
  2. (b) \(\left(\frac{\partial U}{\partial p}\right)_T = -\left(\frac{\partial U}{\partial V}\right)_p \left(\frac{\partial V}{\partial p}\right)_T\)
  3. (c) \(\left(\frac{\partial U}{\partial p}\right)_T = \left(\frac{\partial U}{\partial T}\right)_p \left(\frac{\partial V}{\partial U}\right)_p\)
  4. (d) \(\left(\frac{\partial U}{\partial p}\right)_T = -\left(\frac{\partial U}{\partial V}\right)_T \left(\frac{\partial V}{\partial p}\right)_T\)

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