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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2025 · Paper II, Chemistry · Q101 of 120

Geo-Scientist Prelims 2025 Chemistry Q101: The natural product X (C₈H₁₇N) on zinc distillation followed by…

QuestionNatural products / alkaloids (coniine)

The natural product X (C₈H₁₇N) on zinc distillation followed by KMnO₄ oxidation forms pyridine-2-carboxylic acid. The reaction of X with HI at 300°C under pressure forms n-octane. The compound X consumes two moles of MeI to form quaternary ammonium salt which undergoes Hofmann degradation to form octa-1,4-diene. The subsequent reduction of octa-1,4-diene forms n-octane. On the basis of these chemical evidences, what is the structure of an unknown compound X ?

UPSC Combined Geo-Scientist Prelims 2025 Paper II (Chemistry), Q101: answer options as printed
  1. (a) 1-Methyl-2-ethylpiperidine
  2. (b) 3-Ethyl-2-methylpiperidine
  3. (c) 3-Propylpiperidine
  4. (d) 2-Propylpiperidine

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