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UPSC Combined Geo-Scientist

Chemist

  • 2 objective papers
  • 120 questions each
  • 2 h per paper
  • 100 + 300 marks

Prelims Paper II covers chemistry.

UPSC Combined Geo-Scientist, Prelims · 2025 · Paper II, Chemistry · Q59 of 120

Geo-Scientist Prelims 2025 Chemistry Q59: Which one of the following thermodynamic relations is correct ?

QuestionThermodynamics / Maxwell and fundamental relations

Which one of the following thermodynamic relations is correct ?

  1. (a) \(\left(\frac{\partial S}{\partial T}\right)_p = \frac{1}{T}\left(\frac{\partial H}{\partial T}\right)_p\)
  2. (b) \(\left(\frac{\partial S}{\partial p}\right)_T = \frac{1}{T}\left[\left(\frac{\partial H}{\partial p}\right)_T + V\right]\)
  3. (c) \(\left(\frac{\partial S}{\partial V}\right)_T = \frac{1}{T}\left[p - \left(\frac{\partial U}{\partial T}\right)_V\right]\)
  4. (d) \(\left(\frac{\partial S}{\partial T}\right)_V = -\frac{1}{T}\left(\frac{\partial U}{\partial T}\right)_V\)

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