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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2019 · Mains Paper I

Q1(a). Permanganate and iron(II)

Question

Complete the following reaction and balance it by ion-electron method: MnO₄⁻ + Fe²⁺ + H⁺ →.

Answer in brief

MnO₄⁻ + 5Fe²⁺ + 8H⁺ → Mn²⁺ + 5Fe³⁺ + 4H₂O.

Key points

  • Reduction: MnO₄⁻ + 8H⁺ + 5e⁻ → Mn²⁺ + 4H₂O.
  • Oxidation: Fe²⁺ → Fe³⁺ + e⁻. Multiply by five and add the half-reactions.
  • The five electrons cancel. Charge is -1+10+8=+17 on the left and 2+15=+17 on the right; all atoms also balance.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(a), 2019 Mains Paper I: solution pages 1 and 2
Solution pages 1 and 2 of 18

CoversPermanganateiron(IIRedox balancing