UPSC Combined Geo-Scientist, Mains · 2019 · Mains Paper I
Q1(i). Temperature and conductivity
Question
The electrical conductance of semiconductors increases with temperature unlike those of metals. Why?
Answer in brief
Heating creates many more mobile carriers in a semiconductor; in metals carrier density changes little while scattering increases.
Key points
- In an intrinsic semiconductor, thermal excitation promotes electrons across the band gap, creating electron–hole pairs. Approximately nᵢ∝ e^(-Eg/(2kT)) times a temperature prefactor.
- Conductivity is σ=q(nμₑ+pμₕ). Although phonon scattering reduces mobility, the rapid increase in carrier concentration usually dominates the intrinsic regime.
- In a metal, many carriers already occupy available conduction states. Heating increases lattice vibrations and electron scattering, reducing mobility and conductance.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

CoversTemperatureconductivityBand theory
All parts of Question 1
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- 1(i) Temperature and conductivity5 marks
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