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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2019 · Mains Paper I

Q1(i). Temperature and conductivity

Question

The electrical conductance of semiconductors increases with temperature unlike those of metals. Why?

Answer in brief

Heating creates many more mobile carriers in a semiconductor; in metals carrier density changes little while scattering increases.

Key points

  • In an intrinsic semiconductor, thermal excitation promotes electrons across the band gap, creating electron–hole pairs. Approximately nᵢ∝ e^(-Eg/(2kT)) times a temperature prefactor.
  • Conductivity is σ=q(nμₑ+pμₕ). Although phonon scattering reduces mobility, the rapid increase in carrier concentration usually dominates the intrinsic regime.
  • In a metal, many carriers already occupy available conduction states. Heating increases lattice vibrations and electron scattering, reducing mobility and conductance.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(i), 2019 Mains Paper I: solution pages 3 and 4
Solution pages 3 and 4 of 18

CoversTemperatureconductivityBand theory