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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2016 · Mains Paper II

Q1(h). Reverse osmosis

Question

Explain the term reverse osmosis.

Answer in brief

Reverse osmosis forces solvent from a solution towards the solvent side through a semipermeable membrane by applying pressure exceeding the osmotic-pressure difference.

Key points

  • In ordinary osmosis, solvent moves from the dilute side to the more concentrated side because of the solvent chemical-potential difference.
  • A membrane permeable mainly to solvent retains most dissolved solute. Applying excess pressure to the concentrated side reverses the solvent flux.
  • For an ideal dilute solution, the osmotic pressure is approximately π=cRT (or icRT for a dissociating solute).

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(h), 2016 Mains Paper II: solution pages 3 and 4
Solution pages 3 and 4 of 19

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