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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2016 · Mains Paper II

Q12(b)(i). Raman-scattering lines

Question

What are Rayleigh, Stokes and anti-Stokes lines? Are Stokes and anti-Stokes intensities different? Explain.

Answer in brief

Rayleigh scattering is elastic; Stokes scattering leaves the molecule more energetic, whereas anti-Stokes scattering removes pre-existing molecular excitation.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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CoversRaman-scattering linesRaman spectroscopy

All parts of Question 12