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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2020 · Mains Paper II

Q1(k). Hermitian operators

Question

State the condition for an operator to be Hermitian and prove its eigenvalues are real.

Answer in brief

Â=Â^ on the appropriate domain; every eigenvalue of a normalisable eigenfunction is real.

Key points

  • Hermiticity means ⟨ f|Âg⟩=⟨Âf|g⟩ for allowed states, with boundary conditions that remove any integration-by-parts boundary terms.
  • If Âψ=aψ, then ⟨ψ|Âψ⟩=a⟨ψ|ψ⟩. By Hermiticity the same quantity equals ⟨Âψ|ψ⟩=a*⟨ψ|ψ⟩.
  • Therefore (a-a*)⟨ψ|ψ⟩=0. A nonzero physical state has positive norm, so a=a* and the eigenvalue is real.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(k), 2020 Mains Paper II: solution pages 5 and 6
Solution pages 5 and 6 of 17

CoversHermitian operatorsQuantum mechanics