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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2024 · Mains Paper II

Q5(b). Temperature and adsorption; detergent and surface tension

Question

Explain with reasons: (i) Physical adsorption decreases with increase in temperature, but chemisorption increases. (3 marks) (ii) On adding detergent in water, surface tension decreases. (2 marks)

Answer in brief

(i) Physisorption is exothermic with no activation energy, while chemisorption is activated; (ii) detergent collects at the surface and weakens the inward pull on surface water.

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The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

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Coversphysisorptionchemisorptionadsorption isobarsurfactantGibbs adsorption equation

All parts of Question 5