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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper I covers inorganic chemistry.

UPSC Combined Geo-Scientist, Mains · 2024 · Mains Paper I

Q1(i). Identifying radioactive decay

Question

Which of the curves represent nuclear decay? Justify your answer with mathematical logic. [Graph of activity (A), cpm, against time, h, given in the paper]

Answer in brief

The curved, exponentially decreasing trace represents radioactive decay.

Key points

  • For a single radionuclide, −dN/dt = λN; λ is the decay constant.
  • Integrating gives ln(N/N₀) = −λt, hence N = N₀e−λt.
  • Activity A = λN therefore satisfies A = A₀e−λt. Its slope is −λA and becomes progressively less negative.
  • The curve is convex upwards (d²A/dt² = λ²A > 0), approaching zero asymptotically, not the straight lines.
  • A straight-line decay plot requires ln A against t; its slope is −λ and t₁/₂ = ln 2/λ.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(i), 2024 Mains Paper I: solution pages 9 and 10
Solution pages 9 and 10 of 33

Coversradioactive decay curvefirst-order decaydecay constantactivity vs timehalf-life