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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2017 · Mains Paper II

Q1(b). Adiabatic expansion of helium

Question

Ideal He at 500 K expands adiabatically and reversibly to twice its volume. Calculate the final temperature in degrees Celsius.

Answer in brief

T₂=314.98 K=41.83° C.

Key points

  • Monatomic ideal helium has C_(V,m)=3R/2, C_(p,m)=5R/2 and γ=5/3.
  • For reversible adiabatic expansion, TVγ-1=constant. Hence T₂=T₁(V₁/V₂)γ-1=500(1/2)2/3=314.98 K.
  • Convert only after using absolute temperatures: t₂=T₂-273.15=41.83° C.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(b), 2017 Mains Paper II: solution pages 1 and 2
Solution pages 1 and 2 of 19

CoversAdiabatic expansion of heliumThermodynamics