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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2017 · Mains Paper II

Q1(l). Momentum eigenfunction

Question

Show that y=eⁱᵏˣ is an eigenfunction of Â=-iħ d/dx. Find the eigenvalue.

Answer in brief

 eⁱᵏˣ=ħ k eⁱᵏˣ, so the eigenvalue is ħ k.

Key points

  • An eigenfunction satisfies Ây=ay for a constant eigenvalue a. Differentiate: dy/dx=ik eⁱᵏˣ.
  • Thus Ây=(-iħ)(ik)eⁱᵏˣ=ħ k eⁱᵏˣ, since (-i)i=1.
  • The operator is the x-momentum operator, so the travelling wave has definite momentum pₓ=ħ k and, for a free particle, energy ħ²k²/(2m).
  • The wave number k has unit m⁻¹ and ħ k has unit kg m s⁻¹.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(l), 2017 Mains Paper II: solution pages 5 and 6
Solution pages 5 and 6 of 19

CoversMomentum eigenfunctionQuantum mechanics