UPSC Combined Geo-Scientist, Mains · 2017 · Mains Paper II
Q1(c). Arrhenius acids and bases
Question
Explain the Arrhenius theory of acids and bases with examples.
Answer in brief
An Arrhenius acid increases aqueous H₃O⁺ concentration; an Arrhenius base increases aqueous OH⁻ concentration.
Key points
- An acid ionizes in water, for example HCl + H₂O → H₃O⁺ + Cl⁻.
- A base supplies hydroxide in water, for example NaOH → Na⁺ + OH⁻.
- Neutralisation is H₃O⁺ + OH⁻ → 2H₂O; the spectator ions form the salt. Acid/base strength depends on the extent of ionisation, not merely on concentration.
- The theory is mainly restricted to aqueous behaviour.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

CoversArrhenius acidsbasesAcid–base chemistry
All parts of Question 1
- 1(a) Van der Waals equation8 marks
- 1(b) Adiabatic expansion of helium6 marks
- 1(c) Arrhenius acids and bases6 marks
- 1(d) Carnot efficiency6 marks
- 1(e) Dimerization and temperature6 marks
- 1(f) Zero-order integrated law6 marks
- 1(g) Van't Hoff factor6 marks
- 1(h) Molar absorptivity6 marks
- 1(i) Units of magnetic moment6 marks
- 1(j) Surface tension of isomers5 marks
- 1(k) Water versus hydrogen sulfide5 marks
- 1(l) Momentum eigenfunction6 marks
- 1(m) Atomic emission selection rules8 marks