UPSC Combined Geo-Scientist, Mains · 2018 · Mains Paper II
Q12(a). Infrared-active molecules
Question
Which may show an infrared vibrational absorption spectrum: Cl₂, HCl, NH₃, CO₂ and CH₄?
Answer in brief
HCl, NH₃, CO₂ and CH₄ have IR-active vibrations; Cl₂ does not have an ordinary electric-dipole fundamental.
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CoversInfrared-active moleculesVibrational spectroscopy
All parts of Question 12
- 12(a) Infrared-active molecules5 marks
- 12(b) NMR separation at a different field5 marks
- 12(c) Trinitrobenzene proton spectra5 marks
- 12(d) Carbonyl electronic transitions5 marks