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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2021 · Mains Paper II

Q1(k). Well-behaved functions: two tests

Question

What are well-behaved functions? Which of the following functions are well-behaved? (i) ϕ(x) = e⁻ᵅˣ (α > 0), 0 < x < α; (ii) ϕ(x) = 1/(4 − x), 1 < x < 10.

Answer in brief

A well-behaved function is single-valued, finite, continuous (with a continuous first derivative) and square-integrable. (i) is well-behaved; (ii) is not: it becomes infinite at x = 4.

Key points

  • Well-behaved: single-valued, finite, continuous, continuous dϕ/dx, and ∫|ϕ|² dx finite (normalisable), because ϕ*ϕ dx is a probability.
  • (i) e⁻ᵅˣ: one value at each x; lies between 1 and e⁻ᵅ; continuous, with dϕ/dx = −αe⁻ᵅˣ continuous.
  • ∫e⁻²ᵅˣ dx is finite over 0 to α and even 0 to ∞ (1/2α) ⇒ (i) well-behaved.
  • (ii) 1/(4 − x): x = 4 lies inside 1 < x < 10; ϕ → +∞ from the left, −∞ from the right ⇒ (ii) not well-behaved.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(k), 2021 Mains Paper II: solution pages 11 and 12
Solution pages 11 and 12 of 36

Coverswell-behaved functionacceptable wave functionBorn interpretationnormalisationsquare-integrable