UPSC Combined Geo-Scientist, Mains · 2024 · Mains Paper II
Q1(d). Cubic and tetragonal Bravais lattices
Question
Give an account of Bravais lattices in cubic and tetragonal crystal systems mentioning the minimum symmetry elements in them.
Answer in brief
Cubic: three lattices P, I, F with minimum symmetry four 3-fold axes; tetragonal: two lattices P, I with minimum symmetry one 4-fold axis along c.
Key points
- Cubic, a = b = c, α = β = γ = 90°: primitive P (Z = 1), body-centred I (Z = 2), face-centred F (Z = 4).
- Cubic minimum symmetry: four 3-fold axes along the body diagonals (class 23).
- Tetragonal, a = b ≠ c, α = β = γ = 90°: primitive P (Z = 1) and body-centred I (Z = 2).
- Tetragonal minimum symmetry: one 4-fold axis parallel to c.
- Tetragonal C reduces to a smaller tetragonal P, tetragonal F to tetragonal I; a base-centred cubic lattice loses the 3-fold axes.
The full model answer
As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

CoversBravais latticescubic crystal systemtetragonal crystal systemsymmetry elementsunit cell
All parts of Question 1
- 1(a) Volume and critical temperature of two van der Waals gases5 marks
- 1(b) Second virial coefficient A₂ and the Boyle temperature5 marks
- 1(c) Conductors, semiconductors and insulators: band picture5 marks
- 1(d) Cubic and tetragonal Bravais lattices5 marks
- 1(e) Chemical potential and its change with temperature5 marks
- 1(f) Relation between Kp, Kc and Kx5 marks
- 1(g) Rate constant in dm³ mol⁻¹ s⁻¹5 marks
- 1(h) BET equation and its terms5 marks
- 1(i) Zinc–copper cell from two half-reactions5 marks
- 1(j) Alkaline (sodium) error of the glass electrode5 marks
- 1(k) Commutator of position and d/dx5 marks
- 1(l) Meaning and dimensions of |Ψ(x)|²5 marks
- 1(m) Raman effect against fluorescence and phosphorescence5 marks
- 1(n) H₂: no IR or microwave spectrum, but Raman active5 marks
- 1(o) Fluorescence rate constant of tryptophan5 marks
- 1(p) Why 511 nm light dissociates Br₂ but not H₂5 marks