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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2024 · Mains Paper II

Q1(l). Meaning and dimensions of |Ψ(x)|²

Question

Interpret the physical meaning of the square of the wave function |Ψ(x)|². What are the dimensions of |Ψ(x)|²?

Answer in brief

|Ψ(x)|² is the probability density: |Ψ(x)|² dx is the probability of finding the particle between x and x + dx; in one dimension it has dimensions of length⁻¹ (m⁻¹).

Key points

  • Born interpretation: Ψ itself may be negative or complex; |Ψ|² = Ψ*Ψ is real and ≥ 0: the probability density.
  • Probability in a finite range: P(x₁ → x₂) = ∫ |Ψ|² dx from x₁ to x₂ (area under the curve).
  • Normalisation: ∫ |Ψ|² dx over all space = 1 ⇒ Ψ must be square-integrable.
  • The integral is a pure number and dx is a length ⇒ [|Ψ(x)|²] = L⁻¹ (m⁻¹); Ψ has m⁻¹ᐟ²; in three dimensions |Ψ|² has m⁻³.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(l), 2024 Mains Paper II: solution pages 13 and 14
Solution pages 13 and 14 of 37

CoversBorn interpretationprobability densitywave functionnormalisationdimensions of wave function