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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2024 · Mains Paper II

Q1(k). Commutator of position and d/dx

Question

Evaluate the commutator [x̂, d/dx].

Answer in brief

[x̂, d/dx] = −1; the operators do not commute, hence [x̂, p̂x] = iħ.

Key points

  • An operator identity is found by acting on an arbitrary well-behaved function f(x).
  • [x̂, d/dx]f = x df/dx − d(xf)/dx = x df/dx − (f + x df/dx) = −f (product rule).
  • f is arbitrary ⇒ [x̂, d/dx] = −1; equally [d/dx, x̂] = +1.
  • With p̂x = −iħ d/dx: [x̂, p̂x] = iħ ≠ 0 ⇒ non-commuting operators; uncertainty principle Δx Δpx ≥ ħ/2.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(k), 2024 Mains Paper II: solution pages 13 and 14
Solution pages 13 and 14 of 37

Coverscommutatorposition operatormomentum operator[x, px] = iħuncertainty principle