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UPSC Combined Geo-Scientist

Chemist

  • 3 descriptive papers
  • 200 marks each
  • 3 h per paper

Mains Paper II covers physical chemistry.

UPSC Combined Geo-Scientist, Mains · 2019 · Mains Paper II

Q1(d). Atoms in a BCC sample

Question

An element has bcc structure, edge length 2.88 Å and density 7.20 g cm⁻³. How many atoms are in 104 g?

Answer in brief

The sample contains 1.21×10²⁴ atoms.

Key points

  • A conventional bcc cell contains two atoms. Its edge is 2.88×10⁻⁸ cm, so cell volume is 2.3888×10⁻²³ cm³.
  • The sample volume is 104/7.20=14.444 cm³. Number of cells is sample volume divided by cell volume.
  • Hence N=2(104)/(7.20(2.88×10⁻⁸)³)=1.2094×10²⁴. Equivalently the density data imply molar mass about 51.79 g mol⁻¹, which gives the same count.

The full model answer

As written for the answer booklet: the diagram carries the working, the lines stay short. Read here only; it is not offered as a download.

Model answer to Q1(d), 2019 Mains Paper II: solution pages 1 and 2
Solution pages 1 and 2 of 17

CoversAtoms in a BCC sampleCrystallography